It could be done via modification... I would think many vBulletin developers could make this modification if you made a paid request after you get a license. You might even find one willing to do it in the free requests forum- doesn't hurt to ask.
I have a mod that will redirect users on registration to the URL of the admin's choice so I would think getting something to forward on log-on isn't much different.
The "classroom" could be something you or the user sets via a "custom profile field" which can be setup from the vbulletin admin control panel.
Nothing above is a promise of course- just my best guess as someone who's been here a while.
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