First of all you have an SQL error. Secondly you are trying to log that error to a non existant file.
In ACP goto vBulletin options > Error Handling & Logging - now remove any entries in the log to file boxes, and also set the "Disable Database Error Email Sending" to yes.
Then try and do whatever it is you want to do - if you get any sql errors now then they won't get e-mailed or logged, they will just display the "There seems to have been a slight problem with the xxxxxx database" screen. You can right click in this page and choose "view source" - embedded in the source will be the SQL error you are getting. You can then investiage the reason for the error.
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