There is no style.css file in default vB4. So, that file is from a modification/style you uploaded.
You have many problems with that page. I threw it into an html validator and got 74 Errors, 32 warning(s). And yeah, you can ignore many of what it says, but having two <DOCTYPE> and <html> and <head> and <body> tags in a page is a BIG NO-NO and it will screw up your page.
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