OK. As I wrote in the article, this is not normally the place to ask for things that you want the button to do - this is for the addition of the button, not more.
Anyway: This has nothing to do with PHP - all of this is Javascript. And to open a page in a new window, you would add something like
Code:
window.open("http://www.your-page.com/goes/here.html");
to the exec part of my code. Like so:
Code:
exec: function(editor){
window.open("http://www.your-page.com/goes/here.html");
}
For the additional syntax of window.open just google that command. There's plenty of sites explaining that.