You're still getting that same error even after uploading a new copy? Are you sure you uploaded it to the right place (it should be in inlcudes). Also, it has your database and other config stuff in there so you don't want to upload the copy that came with vbulletin (hopefully you knew that, but just to make sure...).
That error definitely looks like what you get when there's something at the beginning of the config.php file other than <?php
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