The menus on the left side in the admincp are defined in "cpnav_" xml files (stored in the includes/xml folder). The choices in the Options menu are stored in the settinggroup table in the database, and that includes a displayorder value. As someone pointed out above, for imported products this is set in the product xml file. So I think there are 3 ways you could change it: 1) edit the product xml files and reimport the products, 2) put your site in debug mode and edit the setting group in the admincp ("[Edit]" link appears next to setting group name when in debug mode), or 3) you could go in to the database and change the display order directly.
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