Ok, figured this one out... If you have the same trouble in the CMS as I did (Shown in the post above), I fixed it by adding a conditional into the template as shown here;
Code:
<vb:if condition="$show['breadcrumb']">
<vb:if condition="THIS_SCRIPT != 'home'">
<span class="crust" itemscope="itemscope" itemtype="http://data-vocabulary.org/Breadcrumb">
<a href="{vb:raw nav_url}" class="crumb" rel="up" itemprop="url">
<span itemprop="title">{vb:raw nav_title}</span>
</a>
<span class="arrow">
<span>></span>
</span>
</span>
</vb:if>
<vb:else />
<span class="crust" itemscope="itemscope" itemtype="http://data-vocabulary.org/Breadcrumb">
<b class="lastcrumb">
<span itemprop="title">{vb:raw nav_title}</span>
</b>
</span>
</vb:if>
Then add this;
Code:
define('THIS_SCRIPT', 'home');
to the top of "content.php" below the <?php.