[LifesGreatestGift]

To create new links in ModCP do the following

AdminCP>Plugins & Products>Add New Plugin>

Product: vBulletin
Hook Location: mod_index_navigation
Title: ModCP Links
Execution Order: 5 (default)

Plugin PHP Code:

construct_nav_option('Link1', 'link.php');
construct_nav_option('Link2', 'link2.php');
construct_nav_option('Google', 'http://www.google.com');
        construct_nav_group('Links of Interest');
        construct_nav_spacer();

Plugin is Active: Yes

Click Save

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To change the title of the navigation block edit Links of Interest above.
To add more navigation items just copy the construct_nav_option('Link1', 'link.php'); line, edit the Link1 for link title, and link.php for link location. Add as many as you'd like.