Hi
Ahh OK so I am not the only one running an adult oriented vb based site then
Looking at that taboo girls site screenshot (I'm not sure which version of VB that is to be honest) I'd say if it is running on a vb 3.x then they either did a lot of template editing on the templates called from member.php or they are using javascript to rearrange the whole profile page client side after it is output from vbulletin.
My site currently used the latter option to achieve something similar to what they are doing, though i must admit I do rather like their profile layout.
If you are looking to do something like that then you are gonna have to be pretty experienced with php/html and possible javascript/dom as well... or at least able to learn fast lol - you won't do it from options in the ACP
What's the URL of you site?
Rich