For default vBulletin, you can't separate anything ( you can separate just an icon status etc )
but with vBulletin modification you can separate anything
example :
SQL Database for Category GENERAL DISCUSSION ( this category have high traffic ) in Server A
SQL Database for Categoty COMPUTER ( this category have high traffic ) in Server B
All PHP File in Server C
Blog + Groupe + Private Message in server D
but, u need advanced in PHP, Load Balancing, Tweak and etc
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