That sounds like a permissions problem with your super moderators. I no longer have access to an up-to-date vBulletin site (not even for the 3 series), so I cannot direct you to the exact location, but try to look into the Usergroup settings inside your AdminCP.
You might have to either modify the settings for your super moderators or the "Users Awaiting Moderation" group. If you have further trouble with this, I'll need to handle it personally, so please PM me.
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