open admincp, specific the style you wish to change.
There should be 2 templates:
"postbit" & "postbit_legacy".
In it, look for this block:
PHP Code:
<if condition="$post['signature']">
<!-- sig -->
<div>
__________________<br />
$post[signature]
</div>
<!-- / sig -->
</if>
and replace with:
PHP Code:
<if condition="$post['signature']">
<!-- sig -->
<div align="center">
__________________<br />
$post[signature]
</div>
<!-- / sig -->
</if>