Great, I've fixed it!!!
After a lot of trouble and reading again the vBulletin manual I've found an incoherence in config.php file.
It's in this section:
Code:
// ****** MASTER DATABASE USERNAME & PASSWORD ******
// This is the username and password you use to access MySQL.
// These must be obtained through your webhost.
$config['MasterServer']['username'] = 'root';
$config['MasterServer']['password'] = '';
The last two lines were duplicated, the first with a wrong username.
I can't understand how it can be happened but removing that 2 lines the error doesn't appear anymore.
Thanks to everybody.
Bye