You are running a style or a modification that is not compatible with the version of vbulletin you are using.
Add a default vbulletin style that has not been modified and use that. If you still get errors, disable your hooks in your config file with this:
Just below
Add
Code:
define('DISABLE_HOOKS', true);
This will disable all of your modifications. If this works and keeps that error from occuring, remove that line, and start disabling individual modifications to see which one is causing it.
If it turns out to be your style, then you will need to have it updated to work with your version of vbulletin.