[Admin]

The smilies are ordered by their IDs
You can remove all smilies, and re-add them, by the order you want them to show up.

But you can do this.
Find

PHP Code:

$smilies = $DB_site->query("SELECT title, smilietext, smiliepath FROM smilie"); 


and replace it with

PHP Code:

$smilies = $DB_site->query("SELECT title, smilietext, smiliepath FROM smilie ORDER BY title"); 


This will order the smilies by their title. Meaning (Happy) will be before (Sad) but after (Big Grin).