Assuming you're referring to the postbit_legacy styling, open the posbit_legacy template and find:
Code:
<if condition="$show['avatar']">
<div class="smallfont">
<br /><a href="member.php?$session[sessionurl]u=$post[userid]"><img src="$post[avatarurl]" $post[avwidth] $post[avheight] alt="<phrase 1="$post[username]">$vbphrase[xs_avatar]</phrase>" border="0" /></a>
</div>
</if>
Replace with:
Code:
<if condition="$show['avatar']">
<div class="smallfont" style="text-align: center;">
<br /><a href="member.php?$session[sessionurl]u=$post[userid]"><img src="$post[avatarurl]" $post[avwidth] $post[avheight] alt="<phrase 1="$post[username]">$vbphrase[xs_avatar]</phrase>" border="0" /></a>
</div>
</if>