I'm not sure what the code would be if you used that sort of box where users can select one, but if you create a text box where users can enter the program they use, do the following:
Create a profile field.
Now, add the following code to your posbit/postbit_legacy, probably under your reputation.
Quote:
Program:<if condition="$post[fieldXX]"><img src="XXX" border="0px" alt="Photoshop, or whatever program"></a></if>
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Replace the XX in beside field to the profile field number, and the XXX in img src to the image location.
I'm sorry I couldn't help you get exactly what you wanted, maybe someone else can.