Sure,
Go to:
Styles & Templates -> Style Manager -> Your Style -> Edit Templates
in your footer template find:
Code:
<if condition="$show['quickchooser']">
<td class="tfoot">
<select name="styleid" onchange="switch_id(this, 'style')">
<optgroup label="$vbphrase[quick_style_chooser]">
$quickchooserbits
</optgroup>
</select>
</td>
</if>
and change it to:
Code:
<if condition="is_member_of($vbulletin->userinfo, x)">
<if condition="$show['quickchooser']">
<td class="tfoot">
<select name="styleid" onchange="switch_id(this, 'style')">
<optgroup label="$vbphrase[quick_style_chooser]">
$quickchooserbits
</optgroup>
</select>
</td>
</if>
</if>
change
x to the usergroup id of the the users who you want to let use the new style