ah ok, I see
then manually delete all best results from this user
execute the following query:
UPDATE games_list SET bestscore=0,bestmid=0 WHERE bestmid=
UserID
replace
UserID with the UserID of that deleted user
if you have some table_prefix set, remind to put it infront of "games_list" ...
After the query is executed, run the Score Tools -> Update Best Results again to fill up the empty slots with other users